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Sci. , 1980, 22, 171;Stud. Surf. Sci. , 1982, 11, 2 5 5 . , 4 1 7 7 2 0 2 , 1981. , Report FE-2023-9, 1978 (Chem. , 1 9 8 0 , 9 2 , 131 676). R. B. Shavloy and P. J . Reucroft, Univ. o f Kentucky, Inst. Min. , Techn. Report, IMMR 46-PD-80. 128 J . M. Stencel, E. B. Bradley, and F. R. Brown, A p p l . , 1 9 8 0 , 3 4 , 319. 1 2 9 J . Happel and M. A. , 4 151 1 9 1 , 1 9 8 1 . L. H. , 3 9 9 6 2 5 6 , 1980. 131 J . R. Rostrup-Nielsen, K. Pedersen, and I. G. H. Joergensen, Belg. , 8 8 6 7 0 3 , 1981.
134-136 The turnover number (TON: the number of molecules reacting per metal site per second) for Ni-Ti02 catalysts were found to be 1-2 orders of magnitude higher than those for conventional Ni catalysts. Similar results have since been obtained by other workers for the Ni/Ti02 and other similar ~ y s t e m s . l ~ ~An - l ~interesting ~ feature of these results is that whenever the so called 'Strong Metal Support Interaction' (SMSI) occurs, the product selectivity in the reaction of CO with H2 changes towards the production of higher hydrocarbons.
2nd Int. Conf. on Electronic Structure o f the Actinides', ed. J. Mulck, W. Siski, and R . Troc, Polish Acad. Sciences, Warsaw, 1977, p. 357. A. G. Moldovan, A. Elattar, and W. E. Wallace, J. , 1978, 2 5 , 23. I. V. Nicolesen, G. Pop, A. Cobzaru, A. Nicolescu, A. Mihai, H. Florescu, G. Musca, I. Olaru, M. Dardan, and Boteanu, Rom. , 66 388. M. J. Baird and F. W. Steffgen, Ind. Eng. , Prod. Res. , 1977, 16, 142. 32 Catalysis of the use of catalysts based on nickel and other metals for methanation of carbon monoxide.