Download Synthesis And Properties of Low- And High-Molecular by Gennadii Efremovich Zaikov, Irina V. Savenkova, Klara PDF

By Gennadii Efremovich Zaikov, Irina V. Savenkova, Klara Gumargalieva

The most aim of this booklet is to explain the synthesis and homes of low and high-molecular compounds at the quantitative point. unique cognizance was once given to composition fabrics in line with polymers and dispersed wooden, the mechanism of HCL removal reactions through a four-centre transition kingdom in the course of PVC thermal destruction, swelling of the crammed polymer compositions, constitution and homes of mixed structures in accordance with butadiene-nitrile and ternary ethylene-propylene elastomers, intensification mass move procedures in quickly liquid-phase chemical reactions, the examples of hetero-nanophase kinetic description of photochemical reactions, the nanometric particle-like neighborhood buildings and their implications in polymer behaviour, fractal actual chemistry of polymer strategies, amendment of polycyanurates by way of polyethers, polyesters and polyurethanes, hybrid and interpenetrating polymer networks. This assortment comprises articles dedicated to creation of polymers, polymeric combinations, composite and stuffed polymers, questions of increasing life of polymeric articles, biologically lively components, amendment of polymers and polymer-analogous alterations, fractal actual chemistry of polymer ideas, the examine of structural differences in polymers and a few different questions. Of exact awareness also are construction of natural components and defense of our environment.

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Extra info for Synthesis And Properties of Low- And High-Molecular Compounds: Quantitative Level

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Semiempirical method (in parameterization АМ1) and restricted Hartree-Fock method (RHF) with split-valence basic sets: 3-21G(d), 6-31G(d), 6-31G(d, p) and 6-31G(2d) were used to search for a transition state and to calculate thermodynamic parameters of dehydrochlorination reaction. It was expected that addition of d-function to heavy atom and p-function to hydrogen atom would result in correspondence with experimental data. Methods, allowing to take electronic correlation into account are the Moller-Plesset perturbation theory of second order (MP2) with basic sets 6-31G(d), 6-31G(d, p), 6-31G(3d, 3p) and B3LYP/6-31G(d), B3LYP/6-31G(2d) methods [35].

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224 pages. , The Ways to Improve the Utilization of Secondary Wood Raw Materials. Moscow: Lesnaya Prom, , 1988. Kh. Building Materials, Items and Structures. Handbook. Moscow: Vysshaya Shkola, 1990. 495 pages. Izobr. 1 1990. Izobr. 24 1990. Izobr. 16 1990. Izobr. 33 1991. Izobr. 37 1991. Izobr. 2 1986. Izobr. 13 1988. [70] Russ. Patent No. Izobr. No. 37-38 1993. Izobr. 17 1993. [72] . Russ. Patent No. Izobr. No. 15 1994. M.. Inorganic Glues. Leningrad: Khimiya, 1986. 152 pages. F.. The Technology of Plastics.

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